By A. Keller (auth.), Marcel Dosière (eds.)
Since the invention that polymer unmarried crystals are composed of chain folded macromolecules in 1957, the crystallization of polymers has attracted huge curiosity and nonetheless offers attention-grabbing and fruitful parts of study. just a couple of books were absolutely dedicated to the crystallization of polymers long ago.
This publication includes the lawsuits of the NATO ARW dedicated to the `Crystallization of Polymers' which came about in September 1992 on the college of Mons-Hainaut (Belgium). In view of the diversity of papers dedicated to the crystallization of polymers, this publication might be utilized in the following few years as a reference e-book for scientists involved within the box of polymer actual chemistry.
Crystallization of Polymers is principally dedicated to the experimental and theoretical learn of the crystallization of man-made polymers. As a kinetic research of the expansion of polymer crystals must always be preceded by way of a morphological or a structural research, the constitution, the morphology of polymer crystals and extra fairly the lamellar and supralamellar agencies, in addition to the character of the crystal amorphous interface are reviewed and mentioned.
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To conclude it appears that for appropriate polymer crystal structures epitaxial crystallization, notably on low symmetry substrates, becomes an enantioselective process in which the conformation of helices rather than the more classical configuration of molecules is at play. 2. 74 nm c axis repeat distance. By definition, right and left handed helices are isoenergetic. 74 nm built with isochiral helices [7). Recent work on single crystals indicates that the stable, high temperature crystal phase has a four chain unit-cell with a different symmetry.
Dissertation, School of Material Science, Virginia Polytechnic Institute and State University. Alien, R. C. and Mandelkem, L. (1987), Polym. , 17, 473. Mandelkem, L. and Maxfield, J. (1979), 1. Polym. , Polym. Phys. , 17, 1913. , Glotin, M. and Benson, R. S. (1981), Macromolecules, 14,22. Mandelkem, L. (1979) Organization of Macromolecules, in the Condensed Phase, D. A. , Discussion Faraday Society, No. 69, p. 310. Fatou, J. , Marco, C. and Mandelkem, L. (1990), Polymer 31, 1685. Keith, H. D. and Palden, F.
