By Boris Y. Zaslavsky
Covers the basic rules of solute partitioning in aqueous two-phase structures, explains their vital useful beneficial properties, and furnishes equipment of characterization. the knowledge supplied via the partition behaviour of a solute in an aqueous two-phase process is tested
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It seems there is a very long way to go before we establish the proper characteristics of the structure of wateraninaqueous solution. From now on the term "structure of water" willbe used to cover both intermolecular arrange ment and distribution of the water-water H-bonds energies existent a given in aqueous medium. 3. SOLVENT PROPERTIES OF AQUEOUSELECTROLYTE SOLUTIONS The solvent properties of aqueous electrolyte solutions differ from those of aqueous solutions of non-ionic additives due to the presence of th electrostatic forces.
See in [33,55]) was particularly used asa measure of the overall polarity of these mixtures. [51]. The polarity term used in regard to the E~(30)parameter includes the ability of a solvent to participate in the H-bon interactions. ~*,+ 1 5 . 3. Solvent polarity of water-organic solvent mixtures as a function of the concentration of the organic component. Calculated fromdata in [54]. This equation is claimed [56] to hold for40pure solvents including aliphatic alcohols and other H-bon donors. 1Ob) where a and b are empirical coefficients (b-valueis close to the %(30)-value for pure water; a-value is negative and depends on the particular organic solvent studied in mixture with water).
